The HttpUtility class is a part of System.Web in Visual Studio and should be available in .NET 4.0. If you include this library in your application and an error is being generated, check the properties of the project. In the Application tab, the Target framework should not be a Client Profile, but the full framework, i.e. .NET Framework 4 (see image below).
If this doesn’t fix the error, then add System.Web as a reference to your project (see image below).
The error should be corrected after these changes are applied.